Depends on what kind of ship...battleships and carriers have much larger chain links than destroyers, frigates, corvetts, etc. The tiniest real metal chain I've seen could be used on a heavy cruiser, and up. You can find smaller PE chain.

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Try Flyhawk item number 710028.

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Is there anyone who makes metal anchor chain in 1/700 scale?? All I see now are 3d printed versions.